Scientists from Philips Research and the University of Groningen (the Netherlands) have for the first time fabricated arrays of molecular diodes on standard substrates with high yields. The molecular diodes are as thin as one molecule (1.5 nm), and suitable for integration into standard plastic electronics circuits. Based on construction principles known as molecular self-organization, molecular electronics is a promising new approach for manufacturing electronics circuits in addition to today's conventional semiconductor processing.
Dago de Leeuw, a research fellow within Philips Research and member of the joint research team, said, "Molecular electronics will not compete with current silicon-based IC technologies. Molecular electronics could be an interesting option for manufacturing plastic electronics. Plastic electronics is very promising for the manufacture of electronics where low temperature or low cost in-line processing techniques are required."
The technology developed by the scientists at the University of Groningen and Philips Research uses monolayers that are confined to predefined holes in a polymer that has been applied on top of the bottom electrode. The key to their success is the deposition of an additional plastic electrode layer on to the monolayer prior to the deposition of the metallic electrode. The plastic electrode protects the monolayer and as such enables a non-detrimental deposition of the gold electrode.
Dr Bert de Boer, the assistant professor within the Materials Science CentrePlus at the University of Groningen, stated, "Based on a molecular self-assembly process we have developed a reliable way to fabricate well-defined molecular diodes. It will enable us, for the first time, to do reliable and reproducible measurements on molecular junctions, which is essential for the exploration of the potential applications of molecular electronics."
Royal Philips University of Groningen